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IMDG/IMO危險品/海洋污染物的分類及安全、緊急處置(農(nóng)藥部分)

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IMDG/IMO危險品/海洋污染物的分類及安全、緊急處置
(農(nóng)藥部分)
A)	危險品分類
1) 3類易燃液體
2) 4類易燃固體
3) 5類氧化物
4) 6類有毒化合物
5) 8類腐蝕品
6) 9類環(huán)境污染物
1）3類易燃品
定義：包括液體、混合液體、有固體物質(zhì)包含其中的溶液，懸浮液，但這些不包括那些含有其他危險類別的固體物質(zhì)。其閃點：
3.1類：低閃點液體。閉杯閃點< -18°C (0°F) c.c；初沸點≤35°C 
3.2類：中閃點液體。閉杯閃點≥-18°C~23°C (73°F) c.c；初沸點>35°C
3.3類：高閃點液體。閉杯閃點≥23°C~≤61°C（141°F） c.c；初沸點>35°C

包裝：
3.1類：1類包裝（Packing group I），非常危險。如異丙胺
3.2類：2類包裝（Packing group II），中等危險。如甲醇(12°C)、
		   丁醇、甲苯(7°C)、二甲苯(17~23°C)
3.3類：3類包裝（Packing group III），較小危險。如戊醇、己醇、	    
            環(huán)己酮(38~44°C)

2）	4類易燃固體
4.1類：	易燃固體、自反應(yīng)固體
代表物質(zhì)：鋁粉、二硝基苯酚（等硝基化合物）、六亞甲基四胺，硫，磷

4.3類：	與水接觸后，非常危險的物質(zhì)。
代表物質(zhì)：磷化鋅、磷化鎂、磷化鋁，氰氨化鈣等
3）5類氧化物
5.1類：	硝酸銨(化肥)、硝酸鉀（硝酸鹽）、次氯酸鈣(漂白粉)等
5.2類：	有機過氧化物

農(nóng)藥中很少涉及?；て烦隹诓糠稚婕?。

6.1類：有毒化合物
定義：有毒化合物的定義是以該產(chǎn)品的大鼠經(jīng)口(或經(jīng)皮，吸入。通常用經(jīng)口判斷就可以了)的急性半致死中量（LD50）來判斷。
包裝類別	經(jīng)口急性LD50 （IMDG）
     I	             	≤ 5 mg/kg。非常嚴重的中毒危險性。
			該類的產(chǎn)品很少。
     II 	           	> 5 ~ ≤ 50 mg/kg。嚴重的中毒危險性。
 			如：Methomyl 90% SP，Carbofuran 48% SC
     III		固體> 50 ~ ≤ 200 mg/kg。低毒
			液體> 50 ~ ≤ 500 mg/kg。低毒

4）6類有毒化合物
即，理論上來說，固體貨物大鼠經(jīng)口LD50 > 200 mg/kg，液體貨物大鼠經(jīng)口 LD50> 500 mg/kg，就不歸6.1。在沒有其他危險性（如，非腐蝕性、非環(huán)境污染物等）的情況下，就可歸入普貨。但，在實際危包證的出具中，并沒有嚴格的遵循這個規(guī)則，很多9類的固體/粉劑產(chǎn)品也給出具了6.1類的危包。但，這個標準可以作為在無需出具危包證的半危出運中作為參考。6.1類產(chǎn)品比較多。詳見附件介紹！
6.2類：	傳染性物質(zhì) (農(nóng)藥幾無涉及)

對于農(nóng)藥品種來說，歸入該類別的主要產(chǎn)品是乙烯利水劑 （UN3265）。

5）8類腐蝕品
UN3077（S）， UN3082 （L）
對于農(nóng)藥產(chǎn)品來說，絕大多數(shù)的產(chǎn)品，若沒有歸入其他的類別，均可歸入該類別中。

9）9類環(huán)境污染物
附：6.1類有毒化合物 UN No / IMDG code
概述：
如果在運輸過程中需要提供6.1類貨物的IMDG code，大部分的產(chǎn)品，只需要根據(jù)危包證上的UN No，在IMDG手冊上查找，就可以找到對應(yīng)的IMDG code。
在收到的危包證上，各個產(chǎn)品的UN No，留意會發(fā)現(xiàn)，有時不同的有效成分的號是一樣的，而同樣的有效成分的號反而會不一樣。當然，不同的有效成分，UN No也有不一樣的，等等情況。這涉及到產(chǎn)品的不同劑型，毒性，化學類別。
大類產(chǎn)品：

1. 有機磷農(nóng)藥
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。有機磷農(nóng)藥的歸入如下UN No：
2783:	ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
			可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等
2784:	ORGANOPHOSPHORUS PESTICIDE, LIQUID, 
			FLAMMABLE, TOXIC, flash point less than 23 °C
			液體(一般是乳油)，閃點低于23°C c.c.
3017:	ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, 
			FLAMMABLE, flash point not less than 23 °C
			液體(一般是乳油)，閃點大于23°C c.c.，小于61°C c.c.
3018:	ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC
			液體(一般是乳油, 液體農(nóng)藥)，閃點高于61°C c.c.

有機磷農(nóng)藥產(chǎn)品列表：
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。氨基甲酸酯農(nóng)藥歸入如下UN No：
2757:	CARBAMATE PESTICIDE, SOLID, TOXIC
			可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等
2758:	CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, 
			TOXIC, flash point less than 23 °C
			液體(一般是乳油)，閃點低于23°C c.c.
2991:	CARBAMATE PESTICIDE, LIQUID, TOXIC, 
			FLAMMABLE, flash point not less than 23 °C
			液體(一般是乳油)，閃點大于23°C c.c.，小于61°C c.c.
2992:	CARBAMATE PESTICIDE, LIQUID, TOXIC
			液體(一般是乳油，液體農(nóng)藥)，閃點高于61°C c.c.

2. 氨基甲酸酯農(nóng)藥
氨基甲酸酯農(nóng)藥產(chǎn)品列表：
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。擬除蟲菊酯農(nóng)藥歸入如下UN No：
3349:	PYRETHROID PESTICIDE, SOLID, TOXIC
			可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等
3350:	PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, 
			flash point less than 23 °C
			液體(一般是乳油)，閃點低于23°C c.c.
3351:	PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, 
			flash point not less than 23 °C
			液體(一般是乳油)，閃點大于23°C c.c.，小于61°C c.c.
3352:	PYRETHROID PESTICIDE, LIQUID, TOXIC
			液體(一般是乳油，液體農(nóng)藥)，閃點高于61°C c.c.

3. 擬除蟲菊酯
擬除蟲菊酯農(nóng)藥產(chǎn)品列表：
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。香豆素衍生物農(nóng)藥歸入如下UN No：
	3024:	COUMARIN DERIVATIVE PESTICIDE, LIQUID, 
			FLAMMABLE, TOXIC, flash point less than 23 °C
3025:	COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, 
			FLAMMABLE, flash point not less than 23 °C
			液體(一般是母液)，閃點不低于23°C c.c.
3026:	COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC
			液體(一般是母液)，閃點高于61°C c.c.
3027:	COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC
			餌劑、固體原藥等

4. 香豆素衍生物
香豆素衍生物農(nóng)藥產(chǎn)品列表：
	中文名稱	英文名稱
1	溴鼠靈	Brodifacoum
2	溴敵隆	Bromadiolone
3	殺鼠醚	Coumatetralyl
4	氟鼠靈	Flocoumafen
5	殺鼠靈	Warfarin
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。有機氯農(nóng)藥歸入如下UN No：
2761:	ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 
2762:	ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, 
			TOXIC, flash point less than 23 °C
2995:	ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, 
			FLAMMABLE, Flash point not less than 23 °C
2996:	ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC

5. 有機氯農(nóng)藥
背景小知識及產(chǎn)品：
背景小知識：
	有機氯農(nóng)藥是農(nóng)藥發(fā)展史上最為重要的一類化合物，其代表產(chǎn)品為六六六，DDT。而DDT因其在健康方面的貢獻(殺除蚊蟲，控制瘧疾)，其發(fā)明人與1948年獲得了諾貝爾生理/醫(yī)學獎。在二戰(zhàn)期間，因DDT的使用，挽救了成千上萬的性命。DDT后來因發(fā)現(xiàn)其不易降解，在生物體內(nèi)的富集，從而對人和環(huán)境生物造成更為嚴重要的危害而被禁用。若不考慮累計毒性的話，到目前為止，還沒有找到其他能夠與之匹敵的產(chǎn)品：可以在人或人類生活環(huán)境中隨意使用，而不會造成中毒，但卻能夠有效的殺滅蚊蟲，從而取得良好的衛(wèi)生防疫效果。由于殘留嚴重，目前市場上的有機氯產(chǎn)品剩下已經(jīng)不多了。
產(chǎn)品：
	三氯殺螨醇/dicofol、硫丹/endosulfan、三氯殺螨砜/tetradifon

根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。有機錫農(nóng)藥歸入如下UN No：
2786:	ORGANOTIN PESTICIDE, SOLID, TOXIC 
2787:	ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC,
			flash point less than 23 °C
3019:	ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, 
			Flash point not less than 23 °C
3020:	ORGANOTIN PESTICIDE, LIQUID, TOXIC

實際產(chǎn)品中，只有UN2786（WP）、UN3020（SC）
6. 有機錫農(nóng)藥
有機錫農(nóng)藥產(chǎn)品列表：
	中文名稱	英文名稱
1	三唑錫	Azocyclotin
2	三環(huán)錫	Cyhexatin
3	苯丁錫	Fenbutatin Oxide
4	三苯基氫氧化錫
三苯基氫醋酸錫	Fentin hydroxide
Fentin Acetate
5	三磷錫	Phostin
根據(jù)產(chǎn)品的劑型（液體，還是固體），及閃點（液體）的不同。未歸類6.1農(nóng)藥如下UN No：
2588:	PESTICIDE, SOLID, TOXIC, N.O.S.
2902:	PESTICIDE, LIQUID, TOXIC, N.O.S.
2903:	PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S.
			Flash point not less than 23 °C
?3021:	PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., 
			Flash point less than 23 °

7. 其他未歸類6.1農(nóng)藥
復(fù)配產(chǎn)品
煙堿類產(chǎn)品，如吡蟲啉、啶蟲脒等
其他產(chǎn)品，如氟蟲腈、蟲螨腈、多殺菌素、阿維菌素、甲氨基阿維菌素、茚蟲威等
未歸類6.1農(nóng)藥產(chǎn)品列表：
B)	EMS NO.

EMS
Emergency Schedules
危險品應(yīng)急措施代碼

總論
EMS（危險品應(yīng)急措施），著重關(guān)注兩個應(yīng)急措施的方面：
1）火險情況下的緊急應(yīng)對。即，IMO應(yīng)對措施“F - ？”中的“F”
2）泄露情況下的緊急應(yīng)對。即，IMO應(yīng)對措施“S - ？”中的“S”

Emergency Schedules for Fire

EMS code for fire as below:
F – A:	GENERAL FIRE SCHEDULE
F – B:	EXPLOSIVE SUBSTANCES AND ARTICLES
F – C:	NON-FLAMMABLE GASES
F – D:	FLAMMABLE GASES
F – E:	NON-WATER REACTIVE FLAMMABLE LIQUIDS
F – F:	TEMPERATURE CONTROLLED SELF-REACTIVES AND 
			ORGANIC PEROXIDES
F – G:	WATER REACTIVE SUBSTANCES
F – H:	OXIDIZING SUBSTANCES WITH EXPLOSIVE POTENTIAL
F – I:		RADIOACTIVE MATERIAL
F – J:	NON-TEMPERATURE CONTROLLED SELF-REACTIVES 
			AND ORGANIC PEROXIDES

從對F – A到 F – J的適用對象定義，可以看出，農(nóng)藥產(chǎn)品適用的代碼/Code 為“F – A”和“F – E”。

F – A:水劑、懸浮劑、固體、高閃點液體農(nóng)藥：
	如2588、2902
F – E:乳油等含低閃點溶劑易燃農(nóng)藥：
	如2903、3021、1993

Emergency Schedules for Spillage

S – A:	TOXIC SUBSTANCES
S – B:      	CORROSIVE SUBSTANCES
S – C:      	FLAMMABLE, CORROSIVE LIQUIDS
S – D:      	FLAMMABLE LIQUIDS
S – E:      	FLAMMABLE LIQUIDS, FLOATING ON WATER
S – F:      	WATER SOLUBLE MARINE POLLUTANTS
S – G:      	FLAMMABLE SOLIDS AND SELF-REACTIVE SUBSTANCES
S – H:	FLAMMABLE SOLIDS (MOLTEN MATERIAL)
S – I:		FLAMMABLE SOLIDS (REPACKING POSSIBLE)
S – J:		WETTED EXPLOSIVES AND CERTAIN SELF-HEATING 
			SUBSTANCES
S – K:	TEMPERATURE-CONTROLLED SELF-REACTIVE 
			SUBSTANCES
S – L:		SPONTANEOUSLY COMBUSTIBLE, WATER-REACTIVE 
			MATERIAL
 S – M:	HAZARD OF SPONTANEOUS IGNITION

EMS code for spillage as below:
S – N:	SUBSTANCES REACTING VIGOROUSLY WITH WATER
S – O:	SUBSTANCES DANGEROUS WHEN WET (NON-
			COLLECTABLE ARTICLES)
S – P:	SUBSTANCES DANGEROUS WHEN WET (COLLECTABLE 
			ARTICLES)
 S – Q:	OXIDIZING SUBSTANCES
 S – R:	ORGANIC PEROXIDES
 S – S:	RADIOACTIVE MATERIAL
 S – T:	DANGEROUS GOODS WITH BIOHAZARD
?S – U:	GASES (FLAMMABLE, TOXIC OR CORROSIVE)
 S – V:	GASES (NON-FLAMMABLE, NON-TOXIC)
 S – W:	OXIDIZING GASES
?S – X:	EXPLOSIVE ITEMS AND ARTICLES
 S – Y:	EXPLOSIVE CHEMICALS
 S – Z:	TOXIC EXPLOSIVES

從對S – A到 S – Z的適用對象定義，可以看出，農(nóng)藥產(chǎn)品適用的代碼/Code 為:
	S – A, S – B, S – D, S – E, S – F
S – A： 6.1類的水劑、懸浮劑、固體、高閃點液體農(nóng)藥。如UN2588、2902、2783、3018、2757、2992等
S – B：乙烯利水劑，UN3265。
S – D：易/可燃液體農(nóng)藥：如UN2903、3021、2784、3017、2758、2991等
S – E：UN1993
S – F：UN3077、3082

EMS code for Fire
	F – A、F – E
	F – A:	GENERAL FIRE SCHEDULE
	F – E:	NON-WATER REACTIVE 			FLAMMABLE LIQUIDS

Conclusion on EMS code for fire and spillage
EMS code for Spillage
	S – A、S – B、S – D、S – E、S – F
	S – A:	TOXIC SUBSTANCES
	S – B:    	CORROSIVE SUBSTANCES
	S – D:    	FLAMMABLE LIQUIDS
	S – E:     	FLAMMABLE LIQUIDS, 				FLOATING ON WATER
	S – F:     	WATER SOLUBLE MARINE 			POLLUTANTS

Conclusion on EMS code for fire and spillage
其他
危險品貨物描述、順序及其他信息 
?UN Number 
Proper Shipping Name, technical name (if have), 
IMO Class (sub risk), 
Packing Group, 
Flash point (if have), 
Marine pollutant (if have) 
Package quantity (please remarks, if have inter package)
1、The UN number (聯(lián)合國編碼) ：例如，聯(lián)合國編碼是2588，請?zhí)顚憺閁N2588； 
2、Proper Shipping Name (危險貨物正確學名), 如果該貨物有Technical name (Imidacloprid 70% WG), 請?zhí)顚慣echnical name一欄，以下是范例: 
PESTICIDE, SOLID, TOXIC, N.O.S. (Imidacloprid)
Proper shipping name Technical name 
3、IMO Class (危險貨物等級) ：例如，危險等級是6.1，請?zhí)顚憺镃lass 6.1.；如果該類危險品有附 危險等級，請?zhí)钤谥魑ｋU等級后面，例如：5.1(3) 。 
4、Packing group (包裝類別) ：如果該危險品貨物有包裝類別, 請?zhí)峁┌b類別并在前加PG； 例如，包裝類別是III，請?zhí)顚憺镻G III。Packing group分為三種：I, II, III. 如果沒有包裝類別，無需提供包裝 
5、Flash Point (閃點): 如果該危險品貨物有閃點，請?zhí)峁╅W點。 
6、Marine Pollutant (海洋污染): 有N, P, PP三種類別。 
		N：無污染的物質(zhì) 
		P: 有污染性的物質(zhì) 
		PP: 有嚴重污染性的物質(zhì)

其他
常見農(nóng)藥產(chǎn)品危險性描述及其Ems
GLYPHOSATE
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, Solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F

Glyphosate TC and SG:
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Glyphosate SL
2,4-D &amp;amp; ITS ESTER
UN Number	3345	3077
Proper Shipping Name	Phenoxyacetic Acid Derivative Pesticide, Solid, Toxic	Environmentally Hazardous 
Substance, Solid, N.O.S.
IMO Class	6.1	9
Packing Group	III	III
Ems Code	F-A S-A	F-A S-F
2,4-D (acid &amp;amp; salt) TC &amp;amp; SP formulation
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
2,4-D salt SL, 2,4-D ester TC, 2,4-D ester EC (F.p. > 61℃)
UN Number	1993
Proper Shipping Name	Flammable Liquid, N.O.S.
IMO Class	3
Packing Group	I ~III
Ems Code	F-E S-E
2,4-D ester EC (F.p. < 61℃)
Dicamba, MCPA, Picloram, Triclopyr產(chǎn)品危險性分類，除沒有UN3345的類別外，其他同2,4-D產(chǎn)品系列！
PARAQUAT DICHLORIDE DIQUAT DIBROMIDE
UN Number	3016
Proper Shipping Name	Bipyridilium Pesticide, Liquid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
TK and SL
FIPRONIL
UN Number	2588
Proper Shipping Name	Pesticide, Solid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
UN Number	2902
Proper Shipping Name	Pesticide, Liquid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A

Technical material and WDG formulation

SC formulation
ETHEPHON
UN Number	3265
Proper Shipping Name	8
IMO Class	III
Packing Group	CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Ems Code	F-A S-B
Ethephon TC and SL
IMIDACLOPRID, ACETAMIPRID, THIAMETHOXAM, NITENPYRAM, THIACLOPRID
UN Number	2588
Proper Shipping Name	Pesticide, Solid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
Technical material and WP, SP, WG, GR, WS formulation
UN Number	2902
Proper Shipping Name	Pesticide, Liquid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
SL, SC formulation
CARTAP HYDROCHLORIDE
UN Number	2771
Proper Shipping Name	Thiocarbamate Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, Solid, N.O.S..
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
UN Number	2588
Proper Shipping Name	Pesticide, Solid, Toxic, n.o.s.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
由于產(chǎn)品的化學分類不明確，及急性毒數(shù)據(jù)介于低毒~中等毒。這個產(chǎn)品原藥、SP的歸類比較亂。所列的3個UN NO.均可用。

4% GR原則上應(yīng)該是UN3077。但，實際操作時，也有可能被歸入6.1的UN NO.中！
Cartap Hydrochloride TC and SP formulation
Cartap Hydrochloride 4% GR
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, Solid, N.O.S..
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
ABAMECTIN, EMAMECTIN
UN Number	2588
Proper Shipping Name	Pesticide, Solid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
Technical material and WP, SG formulation
UN Number	2902
Proper Shipping Name	Pesticide, Liquid, Toxic, N.O.S. 
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
EC formulation
UN Number	2903	3021
Proper Shipping Name	Pesticide, Liquid, Toxic, Flammable, N.O.S. 
(F.p.: not less than 23 °C)	Pesticide, Liquid, Toxic, Flammable, N.O.S. 
(F.p.: less than 23 °C)
IMO Class	6.1 (3)	3 (6.1)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
ACETOCHLOR, ALACHLOR, BUTACHLOR, METOLACHLOR, PRETILACHLOR
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Technical Material
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
UN Number	1993
Proper Shipping Name	Flammable Liquid, N.O.S. (F.p. < 61℃)
IMO Class	3
Packing Group	III
Ems Code	F-E S-E

EC Formulation
ATRAZINE, AMETRYNE, CYANAZINE, HEXAZINONE, METRIBUZIN, PROMETRYN, PROPAZINE, SIMAZINE, SIMETRYN, TERBUTHYLAZINE, TERBUTRYN
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F

Technical Material and WP, WG formulation
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F

SC Formulation
CYPROCONAZOLE, DIFENOCONAZOLE, DINICONAZOLE(-M), FENBUCONAZOLE, FLUSILAZOLE, FLUTRIAFOL, HEXACONAZOLE, MYCLOBUTANIL, PACLOBUTRAZOL, PROPICONAZOLE, TEBUCONAZOLE, TRIADIMEFON, TRIADIMENOL, TRICYCLZOLE, TRITICONAZOLE, UNICONAZOLE
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Technical Material (Solid) and WP, WG, WS formulation
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F

SC, FS Formulation
UN Number	3082	1993
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.	Flammable Liquid, N.O.S.
(F.p. < 61℃)
IMO Class	9	3
Packing Group	III	III
Ems Code	F-A S-F	F-E S-E
EC Formulation
AZOXYSTROBIN, KRESOXIM-METHYL, TRIFLOXYSTROBIN, PYRACLOSTROBIN
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Technical Material and WG, WS formulation
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
SC, FS Formulation
DICLOFOP-METHYL, FENOXAPROP-P-ETHYL, FLUAZIFOP-P-BUTYL, HALOXYFOP-R-METHYL, QUIZALOFOP-P-ETHYL, CYHALOFOP-BUTYL, QUIZALOFOP-P-TEFURYL, CLODINAFOP-PROPARGYL
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Technical Material
UN Number	3082	1993
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.	Flammable Liquid, N.O.S.
(F.p. < 61℃)
IMO Class	9	3
Packing Group	III	III
Ems Code	F-A S-F	F-E S-E
EC Formulation
ALUMINIUM PHOSPHIDE, ZINC PHOSPHIDE
UN Number	1397
Proper Shipping Name	Aluminium phosphide
IMO Class	4.3 (6.1)
Packing Group	I
Ems Code	F-G S-N

Aluminium phosphide TC &amp;amp; Formulation
UN Number	1714
Proper Shipping Name	Zinc phosphide
IMO Class	4.3 (6.1)
Packing Group	I
Ems Code	F-G S-N
Zinc phosphide TC &amp;amp; Formulation
MANCOZEB, MANEB, PROPINEB, THIRAM, ZIRAM, ZINEB
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
Technical Material &amp;amp; WP, WG formulation
LIQUID: Triazophos, Profenofos, Malathion, Omethoate, Ethoprophos, phenthoate, Phoxim, 
Fenitrothion, Dichlorvos, Ethion, Diazinon, Fenthion, Temephos, Pirimiphos-methyl, Quinalphos
SOLID: Acephate, Chlorpyrifos, Dimethoate, Methidathion, Trichlorofon

ORGANOPHOSPHORUS PESTICIDE/有機磷農(nóng)藥
UN Number	3018	2783
Proper Shipping Name	Organophosphorus Pesticide, Liquid, Toxic	Organophosphorus Pesticide, Solid, Toxic
IMO Class	6.1	6.1
Packing Group	III*	III
Ems Code	F-A S-A	F-A S-A

*) Ethoprophos: 
    Packing group II
TECHNICAL MATERIAL
UN Number	3018
Proper Shipping Name	Organophosphorus Pesticide, Liquid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A

**) Including EC, ULV, 
      SC, EW formulation 
      (if any). F.p. > 61℃
LIQUID FORMULATION**
EC FORMULATION
UN Number	3017	2784
Proper Shipping Name	Organophosphorus Pesticide, Liquid, Toxic, Flammable, 
(F.p. Not less than 23 °C)	Organophosphorus Pesticide, Liquid, Flammable, Toxic, 
(F.p.: Less than 23 °C)
IMO Class	6.1 (3)	3 (6.1)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
UN Number	2783
Proper Shipping Name	Organophosphorus Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
WP, SP, GR FORMULATION
LIQUID: Benfuracarb, Fenobucarb, Carbosulfan
SOLID: Carbaryl, Carbofuran, Isoprocarb, Methomyl, Propoxur, Thiodicarb
CARBAMATE PESTICIDE 氨基甲酸酯農(nóng)藥
UN Number	2992	2757
Proper Shipping Name	Carbamate Pesticide, Liquid, Toxic 	Carbamate Pesticide, Solid, Toxic
IMO Class	6.1	6.1
Packing Group	III	III*
Ems Code	F-A S-A	F-A S-A
TECHNICAL MATERIAL 
*) Carbofuran &amp;amp; Methomyl: 
    Packing group II
UN Number	2992
Proper Shipping Name	Carbamate Pesticide, Liquid, Toxic 
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
LIQUID FORMULATION**
**) Including EC, SC, EW 
       formulation (if any)
       F.p. > 61 ℃
UN Number	2758	2991
Proper Shipping Name	Carbamate Pesticide, Liquid, Flammable, Toxic 
(F.p.: Less than 23 °C)	Carbamate Pesticide, Liquid, Flammable, Toxic 
(F.p.: Not less than 23 °C)
IMO Class	3 (6.1)	6.1(3)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
EC FORMULATION
UN Number	2757
Proper Shipping Name	Carbamate Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III*
Ems Code	F-A S-A

*) Methomyl SP/WP: 
    Packing group II
WP, WDG/DF, SP, GR FORMULATION
LIQUID: Bioallethrin, Cypermethrin, Cyfluthrin, D-allethrin, D-phenothrin, Esbiothrin, Fenpropathrin, 
Fenvalerate, Esfenvalerate, Permethrin
SOLID: Alpha-cypermethrin, Beta-cyfluthrin, Beta-cypermethrin, Bifenthrin, Deltamethrin, Etofenprox, 
Lambda-cyhalothrin, Tetremethrin, 
PYRETHROID PESTICIDE擬除蟲菊酯農(nóng)藥
UN Number	3352	3349
Proper Shipping Name	Pyrethroid Pesticide, Liquid, Toxic	Pyrethroid Pesticide, Solid, Toxic
IMO Class	6.1	6.1
Packing Group	III	III
Ems Code	F-A S-A	F-A S-A
TECHNICAL MATERIAL
UN Number	3352
Proper Shipping Name	Pyrethroid Pesticide, Liquid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
*) Including EC, SC, EW 
     formulation (if any).
     F.p. > 61 ℃
LIQUID FORMULATION*
UN Number	3350	3351
Proper Shipping Name	Pyrethroid Pesticide, Liquid, Flammable, Toxic,
(F.p.: Less than 23 °C)	Pyrethroid Pesticide, Liquid, Flammable, Toxic,
(F.p.: Not less than 23 °C)
IMO Class	3 (6.1)	6.1 (3)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
EC FORMULATION
UN Number	3349
Proper Shipping Name	Pyrethroid Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A

WP, WDG/DF, GR FORMULATION
Coumatetralyl/殺鼠醚、Brodifacoum/溴鼠靈、Bromadiolone/溴敵隆、Warfarin/殺鼠靈
殺鼠劑 / Rodenticide (香豆素類)
UN Number	3027
Proper Shipping Name	Coumarin Derivative Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	II
Ems Code	F-A S-A
TECHNICAL MATERIAL:
UN Number	3027	3025
Proper Shipping Name	Coumarin Derivative Pesticide, Solid, Toxic	Coumarin Derivative Pesticide, Solid, Toxic
IMO Class	6.1	6.1
Packing Group	III	III
Ems Code	F-A S-A	F-A S-A
TECHNICAL CONCENTRATE
UN Number	3027
Proper Shipping Name	Coumarin Derivative Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
BLOCK BAIT*
*) 因餌劑的含量很低(主流含量0.005%)，該產(chǎn)品的急性毒性很低，可歸入普貨。
題外：Warfarin是一種治療心臟病的藥物，用于預(yù)防血管栓塞 
備注：60
Dicofol / 三氯殺螨醇、Endosulfan / 硫丹、Tetradifon /三氯殺螨砜
ORGANOCHLORINE PESTICIDE / 有機氯農(nóng)藥
UN Number	2996
Proper Shipping Name	Organochlorine Pesticide, Liquid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A

TECHNICAL MATERIAL:
UN Number	2762	2995
Proper Shipping Name	Organochlorine Pesticide, Liquid, Flammable, Toxic
(F.p.: Less than 23 °C)	Organochlorine Pesticide, Liquid, Flammable, Toxic
(F.p.: Not less than 23 °C)
IMO Class	3 (6.1)	6.1 (3)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
EC FORMULATION:
Fentin Acetate, Fentin Hydroxide,  Fenbutatin oxide, Cyhexatin, Azocyclotin
ORGANOTIN PESTICIDE 有機錫農(nóng)藥
UN Number	2786
Proper Shipping Name	Organotin Pesticide, Solid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
TECHNICAL MATERIAL AND WP FORMULATION
UN Number	3020
Proper Shipping Name	Organotin Pesticide, Liquid, Toxic
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
SC FORMULATION
復(fù)配產(chǎn)品，其他沒有歸入大類的單劑，根據(jù)
其劑型、毒性、閃點進行歸類。

其他
1) 6.1類固體原藥、制劑產(chǎn)品
UN Number	2588
Proper Shipping Name	Pesticide, Solid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
主要是其他未歸類的中高毒性的殺蟲劑原藥，單劑或復(fù)配的WP、WDG/DF、SP、SG、WS、DS、GR
2) 6.1類液體原藥、液體制劑
UN Number	2902
Proper Shipping Name	Pesticide, Liquid, Toxic, N.O.S.
IMO Class	6.1
Packing Group	III
Ems Code	F-A S-A
主要是其他未歸類的中高毒殺蟲劑液體原藥，SL、SC、EW、OL、EC (F.p. >61°C)產(chǎn)品。如蟲螨腈SC，殺蟲雙SL等
3) 6.1類液體原藥、液體制劑
UN Number	2903	3021
Proper Shipping Name	Pesticide, Liquid, Toxic, Flammable, N.O.S.
(F.p.: Not less than 23 °C)	Pesticide, Liquid, Toxic, Flammable, N.O.S.
(F.p.: Less than 23 °C)
IMO Class	6.1 (3)	3 (6.1)
Packing Group	III	III
Ems Code	F-E S-D	F-E S-D
主要是其他為歸類的中高毒性的殺蟲劑乳油產(chǎn)品。
4) 9類環(huán)境污染物
UN Number	3082
Proper Shipping Name	Environmentally Hazardous Substance, Liquid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
UN Number	3077
Proper Shipping Name	Environmentally Hazardous Substance, solid, N.O.S.
IMO Class	9
Packing Group	III
Ems Code	F-A S-F
殺菌劑、除草劑、低毒殺蟲劑的WP、WDG/DF、SP、SG、GR、
WS、DS產(chǎn)品。如，甲霜靈，氧氯化銅，霜脲氰，異菌脲等的WP，
甲磺隆，苯磺隆，二氯喹啉酸等的WP，WDG

殺菌劑、除草劑、低毒殺蟲劑的SC、SL、EW、EC (F.p. >61℃)產(chǎn)品。
如，百菌清SC，戊唑醇SC，敵草隆SC等

5) 3類易燃液體
UN Number	1993
Proper Shipping Name	Flammable Liquid, N.O.S.
IMO Class	3
Packing Group	I~III
Ems Code	F-E S-E
殺菌劑、除草劑、低毒殺蟲劑乳油產(chǎn)品，大都可歸入該類產(chǎn)品中。

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04-05